The nitrosonium salt [NO][PF6] reacts with [Fe(CO)L(NO)(η3-allyl)][L = P(OPh)3, P(OMe)3, or PPh3; allyl = C3H5, C3H4Me–1, or C3H4Me–2] to give [FeL(NO)2(η3-allyl)][PF6]. Spin saturation transfer 1H n.m.r. spectroscopy shows that the fluxionality of the products involves slow allyl rotation at room temperature.
P. K. Baker, S. Clamp, N. G. Connelly, M. Murray and J. B. Sheridan, J. Chem. Soc., Dalton Trans., 1986, 459 DOI: 10.1039/DT9860000459
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