Selective reductive elimination of Me–R from cis-AuMe2(R)(PPh3) takes place when R is alkenyl, aryl, and furyl, whereas only ethane is reductively eliminated when R is an alkynyl or electron-withdrawing alkyl group.
S. Komiya, S. Ozaki and A. Shibue, J. Chem. Soc., Chem. Commun., 1986, 1555 DOI: 10.1039/C39860001555
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