Mössbauer spectra for the diimine complex Fe(1b)2(NCS)2 provide clear evidence for high-spin iron(II) at room temperature; however for carbon-supported Fe(1b)2(NCS)2 as the loading of the iron complex decreases the high-spin species is converted into the low-spin state.
Y. C. Jean and H. H. Wei, J. Chem. Soc., Chem. Commun., 1986, 1361 DOI: 10.1039/C39860001361
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