On isolated sites of dealuminated Y zeolite the formation of carbenium ions through intermolecular hydride transfer is highly unfavoured and consequently alkane cracking occurs through a monomolecular mechanism with pentaco-ordinate carbonium ions as intermediates.
G. Giannetto, S. Sansare and M. Guisnet, J. Chem. Soc., Chem. Commun., 1986, 1302 DOI: 10.1039/C39860001302
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