The macrobicyclic molecules (1a–c) have been synthesized; they are heteroditopic ligands combining a ‘soft’ and a ‘hard’ binding subunit, which form lateral dinuclear cryptates such as [Rh+–CO, Mn+⊂(1a–c)] by selective complexation to a given site.
A. Carroy and J. Lehn, J. Chem. Soc., Chem. Commun., 1986, 1232 DOI: 10.1039/C39860001232
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