RRKM (Rice–Ramsperger–Kassel–Marcus) calculations, carried out to fit some new experimental data, are found to reconcile apparent differences in two recent studies of the fast reaction between SiH2 and H2: the calculations lead to ΔHf⊖(SiH2)= 65.3 ± 1.5 kcal mol–1.
H. M. Frey, R. Walsh and I. M. Watts, J. Chem. Soc., Chem. Commun., 1986, 1189 DOI: 10.1039/C39860001189
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