The course of the oxidative aminomercriation of prop-2-ynol using secondary aromatic amines depends on the acidity of the reaction medium in such a way that the process may be exclusively directed towards the synthesis of 2,3-bis(N-alkylanilino)propenals (2) or 1,1-bis-(p-alkylaminoaryl)propan-2-ones (3), respectively.
J. Barluenga, F. Aznar and R. Liz, J. Chem. Soc., Chem. Commun., 1986, 1180 DOI: 10.1039/C39860001180
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