Ti(C22H22N4)(C5H5), obtained from the reaction of Ti(C22H22N4)Cl2 with NaC5H5, consists of a minicyclic (C5H5–) and a tetra-aza macrocyclic (C22H22N42–) component bound to TiIII in a new type of sandwich complex the structure of which has been determined by X-ray crystallography.
C. Yang and V. L. Goedken, J. Chem. Soc., Chem. Commun., 1986, 1101 DOI: 10.1039/C39860001101
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