Issue 14, 1986

Dimethylcarbene dimerisation on a raney nickel surface

Abstract

Raney nickel, a highly active heterogeneous catalyst, causes the elimination of N2 from diazopropane quantitatively at 100 °C yielding propene and 40% of tetramethylethylene, an observation further supporting the surface methylene mechanism of the Fischer–Tropsch synthesis.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 1068-1069

Dimethylcarbene dimerisation on a raney nickel surface

H. Bock, G. Tschmutowa and H. P. Wolf, J. Chem. Soc., Chem. Commun., 1986, 1068 DOI: 10.1039/C39860001068

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