Trimethylsilylphosphine undergoes radical initiated addition to Et2NP(CHCH2)2 to form the 1,4-diphosphacyclohexane Et2NP(CH2CH2)2PSiMe3 which, along with the MeOH cleavage products Et2NP(CH2CH2)2PH and MeOP(CH2CH2)2PH, constitute a series of novel 1,4-diphosphacyclohexanes containing oppositely-polarized P–substituent bonds.
M. L. J. Hackney and A. D. Norman, J. Chem. Soc., Chem. Commun., 1986, 850 DOI: 10.1039/C39860000850
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