Issue 9, 1986

Regiochemistry and solvent effect on the reaction of 1-selenoallyl cations with N-methylpyrrole

Abstract

Unsubstituted 1-methylseleno- and/or 1-phenylseleno-allyl cations undergo Friedel–Crafts reaction with N-methylpyrrole at their position 3 to give the adduct (4) while 1-seleno-3-dialkylallyl cations lead to (7) or (9) in a highly solvent dependent manner, presumably via(5) which cannot be isolated.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 688-689

Regiochemistry and solvent effect on the reaction of 1-selenoallyl cations with N-methylpyrrole

M. Renard and L. Hevesi, J. Chem. Soc., Chem. Commun., 1986, 688 DOI: 10.1039/C39860000688

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