The reaction of Ru2(µ-O2CMe)4 with Na2CO3 in aqueous solution has led to the isolation of an orange polymeric air stable compound {Na2[Ru2(µ-O2CO)4]·6H2O}n whose structure has been determined by X-ray crystallographic analysis; this complex exhibits a new co-ordination mode for the carbonate ion.
A. J. Lindsay, M. Motevalli, M. B. Hursthouse and G. Wilkinson, J. Chem. Soc., Chem. Commun., 1986, 433 DOI: 10.1039/C39860000433
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