Issue 4, 1986
From the journal:

Journal of the Chemical Society, Chemical Communications

Intramolecular base–backbone association in 8-bromo-2′,3′-O-isopropylidene-adenosine. Detection of an O(5′)–H ⋯ N(3) hydrogen bond via a long range H(5″)–N(3) spin–spin coupling

Leo H. Koole,   Hans de Boer,   Jan W. de Haan,   Cornelis A. G. Haasnoot,   Pieter van Dael  and  Henk M. Buck  

Abstract

A completely rigid conformation is found for the syn-nucleoside 8-bromo-2′,3′-O-isopropylidene-adenosine in apolar solvents, which is due to an effective O(5′)–H ⋯ N(3) hydrogen bond, as is demonstrated by a substantial N(3) quadrupolar broadening of the H(5″) resonances in the 1H n.m.r. spectra.

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Article information

DOI
https://doi.org/10.1039/C39860000362
Article type
Paper

J. Chem. Soc., Chem. Commun., 1986, 362-364

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Intramolecular base–backbone association in 8-bromo-2′,3′-O-isopropylidene-adenosine. Detection of an O(5′)–H ⋯ N(3) hydrogen bond via a long range H(5″)–N(3) spin–spin coupling

L. H. Koole, H. de Boer, J. W. de Haan, C. A. G. Haasnoot, P. van Dael and H. M. Buck, J. Chem. Soc., Chem. Commun., 1986, 362 DOI: 10.1039/C39860000362

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