At high alkalinities, deprotonation of H3SiO4–(the main vehicle of Si exchange between aqueous silicate species) and its polymers results in reduced polymerization rates and a greater proportion of small silicate units.
S. D. Kinrade and T. W. Swaddle, J. Chem. Soc., Chem. Commun., 1986, 120 DOI: 10.1039/C39860000120
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