The m.c.d. spectra of azobenzene, p-aminobenzene and p-nitroazobenzene in the trans configuration are reported. All spectra present a rather complex structure in the region of the first ππ* absorption band, indicating the presence of more than one transition. The main features of the spectra are analysed with the aid of CNDO/S calculations, permitting an assignment of the various transitions.
G. Marconi and J. Houben, J. Chem. Soc., Faraday Trans. 2, 1985, 81, 975 DOI: 10.1039/F29858100975
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