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The structure of liquid formamide has been examined by X-ray analysis. It is concluded that there are distorted ring dimers which consist of hydrogen-bonded formamide molecules in the liquid state. The most likely model is similar to the crystal structure of formamide.
M. Miyake, O. Kaji, N. Nakagawa and T. Suzuki, J. Chem. Soc., Faraday Trans. 2, 1985, 81, 277 DOI: 10.1039/F29858100277
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