Issue 3, 1985

Electron spin resonance studies of the radicals formed from C-nitroso compounds and olefins. Part 3.—Reactions of fluoro-olefins with trifluoronitrosomethane and with 2,4,6-tribromonitrosobenzene

Abstract

The free-radical-generating reactions of fluorinated alkenes with trifluoronitrosomethane and with 2,4,6-tribromonitrosobenzene have been investigated. In general, two types of radicals are formed, namely RN(O)CF2CXYQ and RN(O)CXYCF2Q, where RNO is the nitroso compound and CF2CXY the alkene; Q is an unknown group and may be different for each type of radical. The former nitroxides predominate at low temperatures and show a large reduction in concentration above ca. 0 °C. Other workers have examined the reactions of trifluoronitrosomethane with fluorinated alkenes, and their findings are compared with ours.

Article information

Article type
Paper

J. Chem. Soc., Faraday Trans. 1, 1985,81, 679-686

Electron spin resonance studies of the radicals formed from C-nitroso compounds and olefins. Part 3.—Reactions of fluoro-olefins with trifluoronitrosomethane and with 2,4,6-tribromonitrosobenzene

L. H. Sutcliffe and A. Zilynk, J. Chem. Soc., Faraday Trans. 1, 1985, 81, 679 DOI: 10.1039/F19858100679

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements