Under the conditions of the Rupe reaction hydration of the triple bond of the perfluorobutylalkynols n-C4F9C![[triple bond, length half m-dash]](https://www.rsc.org/images/entities/char_e007.gif)
CCR(Me)OH occur yielding the ketone n-C4F9CH2COCR(Me)OH; this ketone undergoes intramolecular reaction providing an interesting route to 5-n-perfluoropropylfuran-3(2H)-ones.
L. Gomez, P. Calas and A. Commeyras, J. Chem. Soc., Chem. Commun., 1985, 1493 DOI: 10.1039/C39850001493
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