The addition of a ketone enolate to an ester-substituted nitrone gives an adduct, which upon Hofmann degradation can be elaborated to give a γ-keto-α,β-unsaturated ester, the formal product of a directed aldol condensation.
M. F. Schlecht, J. Chem. Soc., Chem. Commun., 1985, 1239 DOI: 10.1039/C39850001239
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