Issue 18, 1985
From the journal:

Journal of the Chemical Society, Chemical Communications

Determination of the absolute second-order rate constant for the reaction Na + O3→ NaO + O2

David Husain,   Paul Marshall  and  John M. C. Plane  

Abstract

The absolute second-order rate constant for the reaction Na + O3→NaO + O2(k1) has been determined by time-resolved atomic resonance absorption spectroscopy at λ= 589 nm [Na(32PJ)â†� Na(32S1/2)] following pulsed irradiation, coupled with monitoring of O3 by light absorption in the ultra-violet; this yields k1(500 K)= 4(+4,–2)× 10–10 cm3 molecule–1 s–1, resolving large differences for various estimates of this important quantity used in modelling the sodium layer in the mesosphere.

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Article information

DOI
https://doi.org/10.1039/C39850001216
Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 1216-1218

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Determination of the absolute second-order rate constant for the reaction Na + O3→ NaO + O2

D. Husain, P. Marshall and J. M. C. Plane, J. Chem. Soc., Chem. Commun., 1985, 1216 DOI: 10.1039/C39850001216

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