Peripheral substitution of a single face of porphyrin cofacial dimer gives independent control of the oxidation and reduction potentials; use of NH2 as a substituent in one face, and NO2 in the other reduces E′ox–E′red. by almost 0.8 V.
J. A. Cowan and J. K. M. Sanders, J. Chem. Soc., Chem. Commun., 1985, 1214 DOI: 10.1039/C39850001214
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