13 C N.m.r. analysis of ursolic acid produced by cultivation of Perilla frutescens Britt. var. acuta Kudo in the presence of [3,5-13C2]- and [4-2H2,2-13C]-mevalonolactone verified two backbone rearrangements and a 1,2-hydride shift with regard to formation of the D-and E-ring during biosynthesis of ursolic acid.
Y. Tomita, M. Arata and Y. Ikeshiro, J. Chem. Soc., Chem. Commun., 1985, 1087 DOI: 10.1039/C39850001087
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