Partial fragmentation of [Re7C(CO)21]3–, by reaction with I2 in MeCN under Co atmosphere, affords the title compound, which contains a carbide atom at the centre of a tetrahedrally distorted square of rhenium atoms.
T. Beringhelli, G. Ciani, G. D'Alfonso, A. Sironi and M. Freni, J. Chem. Soc., Chem. Commun., 1985, 978 DOI: 10.1039/C39850000978
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