The partial molar volumes of trans-4-dimethylamino-4′-nitroazobenzene in solvents of different polarities are linearly related to the activation volumes in the same solvents for the thermal cis-trans isomerization of this species, which affords unequivocal evidence for an inversion transition state.
N. Nishimura, T. Tanaka and Y. Sueishi, J. Chem. Soc., Chem. Commun., 1985, 903 DOI: 10.1039/C39850000903
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