The alkylation of N,N′-ethylenebis(acetylacetoneiminato)chlorovanadium(III)tetrahydrofuran, [Cl-V(acacen)(thf)]using Grignard reagents gave the corresponding organometallic derivatives [R-V(acacen)]2[R = Me, Ph, PhCH2] having a dimeric Structure, via the sharing of one of the oxygens from the Schiff base, and containing a V-C σ-bond [2.156(7)Å= PhCH2].
S. Gambarotta, M. Mazzanti, C. Floriani, A. Chiesi-Villa and C. Guastini, J. Chem. Soc., Chem. Commun., 1985, 829 DOI: 10.1039/C39850000829
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