Enantiodivergent 1,2- and 1,3-asymmetric induction in α- and β-alkoxyimines is realized via a combination of metal tuning and double stereodifferentiation; the chelation products (5) and (11) are obtained with allyl-MgCl, -AlEt3MgCl+, or -ZnBr, while the non-chelation products (6) and (12) are obtained with allyl-9-borabicyclo[3.3.1]nonane.
Y. Yamamoto, T. Komatsu and K. Maruyama, J. Chem. Soc., Chem. Commun., 1985, 814 DOI: 10.1039/C39850000814
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