Issue 12, 1985

Alkylation of carbonyl compounds with ω-iodo-2-trimethylstannylalk-1-enes. Novel annulation sequences leading to diene systems

Abstract

Alkylation of cyclic ketones and α-methoxycarbonyl ketones with 4-iodo-2-trimethylstannylbut-1-ene and/or 5-iodo-2-trimethylstannylpent-1-ene, and subsequent (Ph3P)4Pd-catalysed cyclization of the enol trifluoromethanesulphonates derived form the alkylation products, from the basis of new annulation sequences which result in the formation of diene systems.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 809-810

Alkylation of carbonyl compounds with ω-iodo-2-trimethylstannylalk-1-enes. Novel annulation sequences leading to diene systems

E. Piers, R. W. Friesen and B. A. Keay, J. Chem. Soc., Chem. Commun., 1985, 809 DOI: 10.1039/C39850000809

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