Issue 11, 1985

Capto-dative stabilisation in amino-substituted radicals

Abstract

The rotational barriers about the C–N bonds in aminoalkyl radicals, H2NĊHR, were found to be significantly greater when R is an acceptor group than when R is an alkyl group; this is good evidence for capto-dative stabilisation of the ground state radicals.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 712-713

Capto-dative stabilisation in amino-substituted radicals

I. MacInnes, J. C. Walton and D. C. Nonhebel, J. Chem. Soc., Chem. Commun., 1985, 712 DOI: 10.1039/C39850000712

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