Irreversible charge-transport through films of electropolymerized 1,1′-bis(chloromethyl)ferrocene
Abstract
Electroactive polymer films, prepared by electroreduction of 1,1′-bis(chloromethyl)ferrocene (BCMF) at a glassy carbon electrode in acetonitrile, act as a selective charge-transport mediator for the reduction of redox couples in the ferrocene state and for the oxidation of the couples in the ferricinium state.