Issue 10, 1985

Preparation and crystal structure of an η-allyl transition metal tetrahydride, tetrahydrido[1,2-bis(diphenylphosphino)ethane](η3-2-isopropylallyl)rhenium

Abstract

Treatment of a mixture of (dppe)ReH7[dppe = 1,2-bis(diphenylphosphino)ethane] and 2,3-dimethylbutadiene successively with ButOK and Me2SO4 affords the complexes the title compound, the X-ray crystal structure of which has been determined.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1985, 670-671

Preparation and crystal structure of an η-allyl transition metal tetrahydride, tetrahydrido[1,2-bis(diphenylphosphino)ethane](η3-2-isopropylallyl)rhenium

D. Baudry, P. Boydell, M. Ephritikhine, H. Felkin, J. Guilhem, C. Pascard and E. T. H. Dau, J. Chem. Soc., Chem. Commun., 1985, 670 DOI: 10.1039/C39850000670

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