Bis(pentamethylcyclopentadienyl)zinc, (Me5C5)2Zn, in the gas phase contains one η5-bonded ring with Zn–C(η5) 230(2) pm and one approximately σ-bonded ring with Zn–C(σ) 209(5) pm; the angle between the Zn–C(σ) bond and the plane defined by the σ-bonded ring is 87(3)°.
R. Blom, A. Haaland and J. Weidlein, J. Chem. Soc., Chem. Commun., 1985, 266 DOI: 10.1039/C39850000266
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