Catalytic decomposition of methanol has been studied on the transition metal carbides TiC, TaC, Mo2C, W2C, and WC; on WC methyl formate was produced with high selectivity (>90%), whereas other catalysts produced mainly CO and H2.
E. Miyazaki, I. Kojima and M. Orita, J. Chem. Soc., Chem. Commun., 1985, 108 DOI: 10.1039/C39850000108
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