N.m.r. and X-ray studies show that reduction of the 16-carbonyl group in the normal and 8,13-isogibberellin series by sodium borohydride affords the 16-endo-alcohols; a 1-carbonyl group affords the 1α-alcohol.
Z. J. Duri, J. R. Hanson and P. B. Hitchcock, J. Chem. Soc., Perkin Trans. 1, 1984, 1099 DOI: 10.1039/P19840001099
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