Temperature programmed diffusion peaks due to α- and β-cage decapsulation are clearly resolved in the Cs, Na-A(O2) system; the latter peak is independent of the degree of Cs exchange whereas the former peak shifts to higher temperature with increasing Cs content.
D. Fraenkel, B. Ittah and M. Levy, J. Chem. Soc., Chem. Commun., 1984, 1389 DOI: 10.1039/C39840001389
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