Internuclear site exchange of a bridging diphenylphosphido ligand is rapid at room temperature for [Rh4(µ-CO)2(CO)4(µ-PPh2)4]; a second higher temperature process allows one PPh2 ligand to migrate between six sites about three Rh–Rh edges.
R. J. Crowte and J. Evans, J. Chem. Soc., Chem. Commun., 1984, 1332 DOI: 10.1039/C39840001332
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