Analytical evidence has been obtained that an oxidized nitrogenous species is formed during the low-temperature thermal decomposition (ca. 500 K) of NH4ClO4; the estimated rate reaction of NO2ClO4 closely accounts for the observed rate of ammonium perchlorate breakdown and nitryl perchlorate is therefore identified as the reaction intermediate.
A. K. Galwey and M. A. Mohamed, J. Chem. Soc., Chem. Commun., 1984, 1197 DOI: 10.1039/C39840001197
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