11-Deoxydaunomycinone (1b) has been synthesized via nucleophilic addition to the alicyclic part and directed lithiation at the aromatic part in the (η6-arene)tricarbonylchromium complexes of the hydronaphthalene derivatives.
M. Uemura, T. Minami and Y. Hayashi, J. Chem. Soc., Chem. Commun., 1984, 1193 DOI: 10.1039/C39840001193
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