From oxidation of the N-aminoquinazolone (2) in methanol, three crystalline products (4), (5), and (6) have been isolated and the structures of two of them confirmed by X-ray crystallography; oxidation of (2) in benzene yields the meta-bridged N-nitrene ‘insertion’ product (3) in 60% yield.
R. S. Atkinson, J. Fawcett, N. A. Gawad, D. R. Russell and L. J. S. Sherry, J. Chem. Soc., Chem. Commun., 1984, 1072 DOI: 10.1039/C39840001072
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