The single-hydrogen bridge attachment of BH4 to iron in the complex FeH(dmpe)2(BH4)[dmpe = 1,2-bis(dimethylphosphino)ethane] is the first reported occurrence of that type of co-ordination of borohydride to iron; a detailed n.m.r. study has demonstrated the facile exchange of the bridging and termibal hydrogen atoms attached to the boron atom.
M. V. Baker and L. D. Field, J. Chem. Soc., Chem. Commun., 1984, 996 DOI: 10.1039/C39840000996
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