A chiral flavin [(S)-3-methyl-10-(1′-hydroxy-3′-methylbutane-2′-yl)isoalloxazine, (1b)] has been synthesised: hydrogen transfer to (1b) and tetra(O-acetyl)riboflavin from chiral NADH model compounds occurred in an asymmetric manner only in the presence of high concentrations of Mg(ClO4)2.
S. Shinkai, H. Nakao, T. Tsuno, O. Manabe and A. Ohno, J. Chem. Soc., Chem. Commun., 1984, 849 DOI: 10.1039/C39840000849
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