Modest stereoselectivity (15–20% enantiomeric excess) is observed in the protonation of the aminoacrylate product that forms in kinetic competition with suicidal capture of the pyridoxal phosphate (PLP) cofactor by that aminoacrylate in the inactivation of a racemase (Pseudomonas striata) with O-acetylserines.
B. Badet, K. Lee, H. G. Floss and C. T. Walsh, J. Chem. Soc., Chem. Commun., 1984, 838 DOI: 10.1039/C39840000838
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