The reaction between N-benzoyl-N′-methyl-N′-phenylthiourea and chloroacetone gives 5-benzoyl-4-methyl-2-(N-methyl-N-phenylamino)thiazole rather than the 5-acetyl-4-phenylisomer which would be predicted from previous work on this route to thiazoles.
G. D. Meakins, M. D. J. Padgham, N. Patel and J. M. Peach, J. Chem. Soc., Chem. Commun., 1984, 837 DOI: 10.1039/C39840000837
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