Ab initio calculations show that the C![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
Si bond length of 1.764 Å in (Me3Si)2SiC(adamantyl)(OSiMe3)is electronically elongated (mainly by OSiMe3)and that the unperturbed r(cSi) is ca. 1.70 Å much chorter than the 1.832 Å measured by electron diffraction.
Y. Apeloig and M. Karni, J. Chem. Soc., Chem. Commun., 1984, 768 DOI: 10.1039/C39840000768
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