SCHEDULED MAINTENANCE:
(η2-olefin)nCr(CO)6-n conplexes result from the photoreactions of Cr(CO)6 with cis-cyclo-octene (n = 1) and trans-cyclo-octene (n = 1, 2); (n = 1,2); (η2-cis-cyclo-octene)Cr(CO)5, isolated as a yellow solid, is labile in solution and serves as a useful Cr(CO)5 transfer reagent to produce various LCr(CO)5 derivatives, including the isotopically labelled hexacarbonyl, Cr(CO)5(13CO).
F. Grevels and V. Skibbe, J. Chem. Soc., Chem. Commun., 1984, 681 DOI: 10.1039/C39840000681
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