Issue 11, 1984
From the journal:

Journal of the Chemical Society, Chemical Communications

Trimethylenemethane complexes of osmium and iridium; crystal structure of η4-trimethylenemethanechlorocarbonyltriphenylphosphineiridium

Michael D. Jones,   Raymond D. W. Kemmitt,   Andrew W. G. Platt,   David R. Russell  and  Lesley J. S. Sherry  

Abstract

The η4-trimethylenemethane complexes [Os{η4C(CH2)3}(CO)2(PPh3)], [Ir{η4-C(CH2)3}(Cl)(CO)(PPh3)], and [Ir{η4-C(CH2)3}(CO)(PPh3)2][PF6] have been prepared by treating [Os(CO)2(PPh3)3] with Me3SiCH2C([double bond, length half m-dash]CH2)CH2OAc, trans-[IrCl(CO)(PPh3)2] with Me3SiCH2C([double bond, length half m-dash]CH2)CH2Cl, and trans-[IrCl(CO)(PPh3)2] plus KPF6 with Me3SiCH2C([double bond, length half m-dash]CH2)CH2Cl, respectively; the X-ray crystal structure of [Ir{η4-C(CH2)3}(Cl)(CO)(PPh3)] indicates that the trimethylenemethane is not symmetrically bound to the iridium.

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Article information

DOI
https://doi.org/10.1039/C39840000673
Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 673-674

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Trimethylenemethane complexes of osmium and iridium; crystal structure of η4-trimethylenemethanechlorocarbonyltriphenylphosphineiridium

M. D. Jones, R. D. W. Kemmitt, A. W. G. Platt, D. R. Russell and L. J. S. Sherry, J. Chem. Soc., Chem. Commun., 1984, 673 DOI: 10.1039/C39840000673

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