Zn2+ ions octahedrally co-ordinated in a non-stoicheiometric Zn–Cr spinel-like phase are the active sites in the catalytic synthesis of methanol from syngas at high temperature.
G. D. Piero, F. Trifiro and A. Vaccari, J. Chem. Soc., Chem. Commun., 1984, 656 DOI: 10.1039/C39840000656
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