The Solid state structure of [IrCl(PF3)2]2 consists of infinite zig-zag chains of iridium atoms with short inter-and intra-molecular Ir ⋯ Ir contacts; by contrast related complexes containing PF2NMe2 do not appear to have extended metal–metal interactions.
P. B. Hitchcock, S. Morton and J. F. Nixon, J. Chem. Soc., Chem. Commun., 1984, 603 DOI: 10.1039/C39840000603
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