Extended metal–metal interactions in fluorophosphine complexes of iridium(I)
Abstract
The Solid state structure of [IrCl(PF3)2]2 consists of infinite zig-zag chains of iridium atoms with short inter-and intra-molecular Ir ⋯ Ir contacts; by contrast related complexes containing PF2NMe2 do not appear to have extended metal–metal interactions.