Heat-treatment of chloro(tetraphenylporphyrinato)iron(III)(CITPPFeIII) in an Ar atmosphere gives a product with an anomalously high molar magnetic susceptibility, and on it the cathodic reduction of oxygen occurs through a 4-electron pathway, namely oxygen to water.
O. Ikeda, H. Fukuda and H. Tamura, J. Chem. Soc., Chem. Commun., 1984, 567 DOI: 10.1039/C39840000567
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