Issue 6, 1984

Non-limiting solvolysis of a 2-propyl sulphonate in trifluoroacetic acid. A redetermination of deuterium kinetic isotope effects

Abstract

Contrary to an earlier report, the α-deuterium isotope effect (kH/kD) for the trifluoroacetolysis of a 2-propyl arenesulphonate is smaller than 1.22 at 25 °C, suggesting that the reaction does not proceed via the limiting SN1 mechanism.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1984, 362-363

Non-limiting solvolysis of a 2-propyl sulphonate in trifluoroacetic acid. A redetermination of deuterium kinetic isotope effects

H. Yamataka, S. Tamura, T. Hanafusa and T. Ando, J. Chem. Soc., Chem. Commun., 1984, 362 DOI: 10.1039/C39840000362

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