Tertiary amines of low steric hindrance readily displace bromide ion from bromodifluoroborane adducts of tertiary amines, D·BF2Br (D = donor), to form bis(tertiary-amine)difluoroboron cations, D2BF2+ and DD'BF2+.
M. J. Farquharson and J. S. Hartman, J. Chem. Soc., Chem. Commun., 1984, 256 DOI: 10.1039/C39840000256
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